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utional caves or karst caves are the most frequently occurring caves. Such caves form in rock that is soluble; most occur in limestone, but they can also form in other rocks including chalk, dolomite, marble, salt, and gypsum. Rock is dissolved by natural acid in groundwater that seeps through bedding planes, faults, joints, and comparable features. Over time cracks enlarge to become caves and cave systems. The largest and most abundant solutional caves are located in limestone. Limestone dissolves under the action of rainwater and groundwater charged with H2CO3 (carbonic acid) and naturally occurring organic acids. The dissolution process produces a distinctive landform known as karst, characterized by sinkholes and underground drainage. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include flowstones, stalactites, stalagmites, helictites, soda straws and columns. T
hese secondary mineral deposits in caves are called speleothems. The portions of a solutional cave that are below the water table or the local level of the groundwater will be flooded. Lechuguilla Cave in New Mexico and nearby Carlsbad Cavern are now believed to be examples of another type of solutional cave. They were formed by H2S (hydrogen sulfide) gas rising from below, where reservoirs of oil give off sulfurous fumes. This gas mixes with groundwater and forms H2SO4 (sulfuric acid). The acid then dissolves the limestone from below, rather than from above, by acidic water percolating from the surface. Primary Exploring a lava tube in Hawaii. Caves formed at the same time as the surrounding rock are called primary caves. Lava tubes are formed through volcanic activity and are the most common pri